You should start by reading on what vectors are and how they work. Get rid of the while loop. You only need 2 for loops to accomplish the task with the way your code is set up.
vector<float> cash;
......
......
for (int i = 0; i < 5; i++)
{
cout << "Enter the cost of the item: ";
cin >> item;
//push items into vector here
}
.....
.....
for (int i = 0; i < cash.size(); i++)
{
// output like you were doing but with your vector elements
}
With that skeleton code you should be able to accomplish what you want with a little research