Ajax jquery async return value

This is not possible.
Javascript runs on the UI thread; if your code waits for the server to reply, the browser must remain frozen.

Instead, you need to return the value using a callback:

function get_char_val(merk, callback)
{  
    var returnValue = null;
    $.ajax({   
                type:       "POST",
                url:            "char_info2.php",   
                data:   { name: merk },   
                dataType: "html",  
                success:    function(data) {
                    callback(data);
                } 
        }); 
}

get_char_val('x', function(px) { ... });
get_char_val('y', function(py) { ... });

Note that the two callbacks will run in an unpredictable order.

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You should modify your design so that you can get all twenty values in a single AJAX request.
For example, you can take a comma-separated list of values, and return a JSON object like { x: "...", y: "..." }.