How can split a string which contains only delimiter?

Alnitak is correct that trailing empty strings will be discarded by default.

If you want to have trailing empty strings, you should use split(String, int) and pass a negative number as the limit parameter.

The limit parameter controls the number of times the
pattern is applied and therefore affects the length of the resulting
array. If the limit n is greater than zero then the pattern
will be applied at most n – 1 times, the array’s
length will be no greater than n, and the array’s last entry
will contain all input beyond the last matched delimiter. If n
is non-positive then the pattern will be applied as many times as
possible and the array can have any length. If n is zero then
the pattern will be applied as many times as possible, the array can
have any length, and trailing empty strings will be discarded.

Note that split(aString) is a synonym for split(aString, 0):

This method works as if by invoking the two-argument split method with the given expression and a limit argument of zero. Trailing empty strings are therefore not included in the resulting array.

Also, you should use a loop to get the values from the array; this avoids a possible ArrayIndexOutOfBoundsException.

So your corrected code should be (assuming you want the trailing empty strings):

String sample = "::";
String[] splitTime = sample.split(":", -1);
for (int i = 0; i < splitTime.length; i++) {
    System.out.println("Value " + i + " : \"" + splitTime[i] + "\"");
}

Output:

Value 0 : ""
Value 1 : ""
Value 2 : ""

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