Easy, you can use a Post request and submit your file as binary (byte array).
String url = "http://yourserver";
File file = new File(Environment.getExternalStorageDirectory().getAbsolutePath(),
"yourfile");
try {
HttpClient httpclient = new DefaultHttpClient();
HttpPost httppost = new HttpPost(url);
InputStreamEntity reqEntity = new InputStreamEntity(
new FileInputStream(file), -1);
reqEntity.setContentType("binary/octet-stream");
reqEntity.setChunked(true); // Send in multiple parts if needed
httppost.setEntity(reqEntity);
HttpResponse response = httpclient.execute(httppost);
//Do something with response...
} catch (Exception e) {
// show error
}