How to add buttons dynamically to my form?

You aren’t creating any buttons, you just have an empty list.

You can forget the list and just create the buttons in the loop.

private void button1_Click(object sender, EventArgs e) 
{     
     int top = 50;
     int left = 100;

     for (int i = 0; i < 10; i++)     
     {         
          Button button = new Button();   
          button.Left = left;
          button.Top = top;
          this.Controls.Add(button);      
          top += button.Height + 2;
     }
}