Here is an example that does a union between two completely unrelated tables: the Student and the Products table. It generates an output that is 4 columns:
select
FirstName as Column1,
LastName as Column2,
email as Column3,
null as Column4
from
Student
union
select
ProductName as Column1,
QuantityPerUnit as Column2,
null as Column3,
UnitsInStock as Column4
from
Products
Obviously you’ll tweak this for your own environment…