Context.openFileOutput is meant to be used for creating files private to your application. they go in your app’s private data directory. you supply a name, not a path: “name The name of the file to open; can not contain path separators”.
http://developer.android.com/reference/android/content/Context.html#openFileOutput(java.lang.String, int)
as for your question, you can’t write to / unless you’re root:
my-linux-box$ adb shell ls -l -d /
drwxr-xr-x root root 2010-01-16 07:42
$
i don’t know what your API is that expects you to write to the root directory, but i’m guessing it’s not an Android API and you’re reading the wrong documentation 😉