You can get the width and height of PDF document like below,
var doc = new jsPDF("p", "mm", "a4");
var width = doc.internal.pageSize.getWidth();
var height = doc.internal.pageSize.getHeight();
Then you can use this width and height for your image to fit the entire PDF document.
var imgData="data:image/jpeg;base64,/9j/4AAQSkZJ......";
doc.addImage(imgData, 'JPEG', 0, 0, width, height);
Make sure that your image has the same size (resolution) of the PDF document. Otherwise it will look distorted (stretched).
If you want convert px
to mm
use this link http://www.endmemo.com/sconvert/millimeterpixel.php