If you have XDocument it is easier to use LINQ-to-XML:
var document = XDocument.Load(fileName);
var name = document.Descendants(XName.Get("Name", @"http://demo.com/2011/demo-schema")).First().Value;
If you are sure that XPath is the only solution you need:
using System.Xml.XPath;
var document = XDocument.Load(fileName);
var namespaceManager = new XmlNamespaceManager(new NameTable());
namespaceManager.AddNamespace("empty", "http://demo.com/2011/demo-schema");
var name = document.XPathSelectElement("/empty:Report/empty:ReportInfo/empty:Name", namespaceManager).Value;