Ignore Duplicates and Create New List of Unique Values in Excel

Totero’s answer is correct. The link is also very helpful.

Basically the formula you need is:

B2=INDEX($A$2:$A$20, MATCH(0, COUNTIF($B$1:B1, $A$2:$A$20), 0))

Then press ctrl+shift+enter (or it will not work using a array formula).

Two important things to keep in mind here: The complete list is in cells A2:A20, then this formula has to be pasted in cell B2 (Not B1 as that will give you circular reference).
Secondly this is an array formula, so you need to press ctrl+shift+enter or it will not work correctly.

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