ISO-8859-1 encoding and binary data preservation

"\u00F6" is not a byte array. It’s a string containing a single char. Execute the following test instead:

public static void main(String[] args) throws Exception {
    byte[] b = new byte[] {(byte) 0x00, (byte) 0xf6};
    String s = new String(b, "ISO-8859-1"); // decoding
    byte[] b2 = s.getBytes("ISO-8859-1"); // encoding
    System.out.println("Are the bytes equal : " + Arrays.equals(b, b2)); // true
}

To check that this is true for any byte, just improve the code an loop through all the bytes:

public static void main(String[] args) throws Exception {
    byte[] b = new byte[256];
    for (int i = 0; i < b.length; i++) {
        b[i] = (byte) i;
    }
    String s = new String(b, "ISO-8859-1");
    byte[] b2 = s.getBytes("ISO-8859-1");
    System.out.println("Are the bytes equal : " + Arrays.equals(b, b2));
}

ISO-8859-1 is a standard encoding. So the language used (Java, C# or whatever) doesn’t matter.

Here’s a Wikipedia reference that claims that every byte is covered:

In 1992, the IANA registered the character map ISO_8859-1:1987, more commonly known by its preferred MIME name of ISO-8859-1 (note the extra hyphen over ISO 8859-1), a superset of ISO 8859-1, for use on the Internet. This map assigns the C0 and C1 control characters to the unassigned code values thus provides for 256 characters via every possible 8-bit value.

(emphasis mine)