Create an array of sizes in the order you want them to be in, then sort the shirts by the position of their sizes in that array:
string[] sizes = new [] {"XS", "S", "M", "L", "XL", "XXL", "UK 10", "UK 12"};
var shirtsInOrder = shirts
.OrderBy(s=>sizes.Contains(s) ? "0" : "1") // put unmatched sizes at the end
.ThenBy(s=>Array.IndexOf(sizes,s)) // sort matches by size
.ThenBy(s=>s); // sort rest A-Z