>>> df.groupby('id').first()
value
id
1 first
2 first
3 first
4 second
5 first
6 first
7 fourth
If you need id
as column:
>>> df.groupby('id').first().reset_index()
id value
0 1 first
1 2 first
2 3 first
3 4 second
4 5 first
5 6 first
6 7 fourth
To get n first records, you can use head():
>>> df.groupby('id').head(2).reset_index(drop=True)
id value
0 1 first
1 1 second
2 2 first
3 2 second
4 3 first
5 3 third
6 4 second
7 4 fifth
8 5 first
9 6 first
10 6 second
11 7 fourth
12 7 fifth