You almost certainly want to declare next_command as a pointer. Having a structure that contains itself isn’t possible (in any language).
I think this is what you want:
class EthercatDatagram(Structure):
pass
EthercatDatagram._fields_ = [
("header", EthercatDatagramHeader),
("packet_data_length", c_int),
("packet_data", c_char_p),
("work_count", c_ushort),
("next_command", POINTER(EthercatDatagram))]