Using DataFrame.update, which aligns on indices (https://pandas.pydata.org/pandas-docs/stable/generated/pandas.DataFrame.update.html):
>>> df1.set_index('Code', inplace=True)
>>> df1.update(df2.set_index('Code'))
>>> df1.reset_index() # to recover the initial structure
Code Name Value
0 1 Company1 200.0
1 2 Company2 1000.0
2 3 Company3 400.0