What does “SSLError: [SSL] PEM lib (_ssl.c:2532)” mean using the Python ssl library?

Assuming that version 3.6 is being used:

See: https://github.com/python/cpython/blob/3.6/Modules/_ssl.c#L3523-L3534

 PySSL_BEGIN_ALLOW_THREADS_S(pw_info.thread_state);
 r = SSL_CTX_check_private_key(self->ctx);
 PySSL_END_ALLOW_THREADS_S(pw_info.thread_state);
 if (r != 1) { 
    _setSSLError(NULL, 0, __FILE__, __LINE__);
    goto error;
 }

What it is saying is that SSL_CTX_check_private_key failed; thus, the private key is not correct.

Reference to the likely version:

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