I don’t pretend to fully understand what’s going on behind the scenes, but here’s a workaround that works for me:
# Problem: CMake runs toolchain files multiple times, but can't read cache variables on some runs.
# Workaround: On first run (in which cache variables are always accessible), set an intermediary environment variable.
if (FOO)
# Environment variables are always preserved.
set(ENV{_FOO} "${FOO}")
else ()
set(FOO "$ENV{_FOO}")
endif ()