Creating a specific XML document using namespaces in C#

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You should try it that way

  XmlDocument doc = new XmlDocument();  

  XmlSchema schema = new XmlSchema();
  schema.Namespaces.Add("xmlns", "http://www.sample.com/file");

  doc.Schemas.Add(schema);

Do not forget to include the following namespaces:

using System.Xml.Schema;
using System.Xml;

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