I Was going to suggest to use get_meta_tags() but it seems to not work (for me) :s
<?php
$tags = get_meta_tags('http://www.example.com/');
echo $tags['og:image'];
?>
But I would rather suggest using DOMDocument anyways:
<?php
$sites_html = file_get_contents('http://example.com');
$html = new DOMDocument();
@$html->loadHTML($sites_html);
$meta_og_img = null;
//Get all meta tags and loop through them.
foreach($html->getElementsByTagName('meta') as $meta) {
//If the property attribute of the meta tag is og:image
if($meta->getAttribute('property')=='og:image'){
//Assign the value from content attribute to $meta_og_img
$meta_og_img = $meta->getAttribute('content');
}
}
echo $meta_og_img;
?>
Hope it helps