Your json_decoded
object is a Python dictionary; you can simply add your key to that, then re-encode and rewrite the file:
import json
with open(json_file) as json_file:
json_decoded = json.load(json_file)
json_decoded['ADDED_KEY'] = 'ADDED_VALUE'
with open(json_file, 'w') as json_file:
json.dump(json_decoded, json_file)
I used the open file objects as context managers here (with the with
statement) so Python automatically closes the file when done.