You can run the dropdb command from the command line:
dropdb 'database name'
Note that you have to be a superuser or the database owner to be able to drop it.
You can also check the pg_stat_activity
view to see what type of activity is currently taking place against your database, including all idle processes.
SELECT * FROM pg_stat_activity WHERE datname="database name";
Note that from PostgreSQL v13 on, you can disconnect the users automatically with
DROP DATABASE dbname WITH (FORCE);
or
dropdb -f dbname