How to find the last occurrence of an item in a Python list

If you are actually using just single letters like shown in your example, then str.rindex would work handily. This raises a ValueError if there is no such item, the same error class as list.index would raise. Demo:

>>> li = ["a", "b", "a", "c", "x", "d", "a", "6"]
>>> ''.join(li).rindex('a')
6

For the more general case you could use list.index on the reversed list:

>>> len(li) - 1 - li[::-1].index('a')
6

The slicing here creates a copy of the entire list. That’s fine for short lists, but for the case where li is very large, efficiency can be better with a lazy approach:

def list_rindex(li, x):
    for i in reversed(range(len(li))):
        if li[i] == x:
            return i
    raise ValueError("{} is not in list".format(x))

One-liner version:

next(i for i in reversed(range(len(li))) if li[i] == 'a')

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