How to generate entire DDL of an Oracle schema (scriptable)?

You can spool the schema out to a file via SQL*Plus and dbms_metadata package. Then replace the schema name with another one via sed. This works for Oracle 10 and higher.

sqlplus<<EOF
set long 100000
set head off
set echo off
set pagesize 0
set verify off
set feedback off
spool schema.out

select dbms_metadata.get_ddl(object_type, object_name, owner)
from
(
    --Convert DBA_OBJECTS.OBJECT_TYPE to DBMS_METADATA object type:
    select
        owner,
        --Java object names may need to be converted with DBMS_JAVA.LONGNAME.
        --That code is not included since many database don't have Java installed.
        object_name,
        decode(object_type,
            'DATABASE LINK',      'DB_LINK',
            'JOB',                'PROCOBJ',
            'RULE SET',           'PROCOBJ',
            'RULE',               'PROCOBJ',
            'EVALUATION CONTEXT', 'PROCOBJ',
            'CREDENTIAL',         'PROCOBJ',
            'CHAIN',              'PROCOBJ',
            'PROGRAM',            'PROCOBJ',
            'PACKAGE',            'PACKAGE_SPEC',
            'PACKAGE BODY',       'PACKAGE_BODY',
            'TYPE',               'TYPE_SPEC',
            'TYPE BODY',          'TYPE_BODY',
            'MATERIALIZED VIEW',  'MATERIALIZED_VIEW',
            'QUEUE',              'AQ_QUEUE',
            'JAVA CLASS',         'JAVA_CLASS',
            'JAVA TYPE',          'JAVA_TYPE',
            'JAVA SOURCE',        'JAVA_SOURCE',
            'JAVA RESOURCE',      'JAVA_RESOURCE',
            'XML SCHEMA',         'XMLSCHEMA',
            object_type
        ) object_type
    from dba_objects 
    where owner in ('OWNER1')
        --These objects are included with other object types.
        and object_type not in ('INDEX PARTITION','INDEX SUBPARTITION',
           'LOB','LOB PARTITION','TABLE PARTITION','TABLE SUBPARTITION')
        --Ignore system-generated types that support collection processing.
        and not (object_type="TYPE" and object_name like 'SYS_PLSQL_%')
        --Exclude nested tables, their DDL is part of their parent table.
        and (owner, object_name) not in (select owner, table_name from dba_nested_tables)
        --Exclude overflow segments, their DDL is part of their parent table.
        and (owner, object_name) not in (select owner, table_name from dba_tables where iot_type="IOT_OVERFLOW")
)
order by owner, object_type, object_name;

spool off
quit
EOF

cat schema.out|sed 's/OWNER1/MYOWNER/g'>schema.out.change.sql

Put everything in a script and run it via cron (scheduler). Exporting objects can be tricky when advanced features are used. Don’t be surprised if you need to add some more exceptions to the above code.