I’ve finally made it working and easy for debugging.
My final method code for those interested:
/// <summary>
/// Prints the PDF.
/// </summary>
/// <param name="ghostScriptPath">The ghost script path. Eg "C:\Program Files\gs\gs8.71\bin\gswin32c.exe"</param>
/// <param name="numberOfCopies">The number of copies.</param>
/// <param name="printerName">Name of the printer. Eg \\server_name\printer_name</param>
/// <param name="pdfFileName">Name of the PDF file.</param>
/// <returns></returns>
public bool PrintPDF (string ghostScriptPath, int numberOfCopies, string printerName, string pdfFileName) {
ProcessStartInfo startInfo = new ProcessStartInfo();
startInfo.Arguments = " -dPrinted -dBATCH -dNOPAUSE -dNOSAFER -q -dNumCopies=" + Convert.ToString(numberOfCopies) + " -sDEVICE=ljet4 -sOutputFile=\"\\\\spool\\" + printerName + "\" \"" + pdfFileName + "\" ";
startInfo.FileName = ghostScriptPath;
startInfo.UseShellExecute = false;
startInfo.RedirectStandardError = true;
startInfo.RedirectStandardOutput = true;
Process process = Process.Start(startInfo);
Console.WriteLine( process.StandardError.ReadToEnd() + process.StandardOutput.ReadToEnd() );
process.WaitForExit(30000);
if (process.HasExited == false) process.Kill();
return process.ExitCode == 0;
}