In order for System.loadLibrary() to work, the library (on Windows, a DLL) must be in a directory somewhere on your PATH or on a path listed in the java.library.path system property (so you can launch Java like java -Djava.library.path=/path/to/dir).
Additionally, for loadLibrary(), you specify the base name of the library, without the .dll at the end. So, for /path/to/something.dll, you would just use System.loadLibrary("something").
You also need to look at the exact UnsatisfiedLinkError that you are getting. If it says something like:
Exception in thread "main" java.lang.UnsatisfiedLinkError: no foo in java.library.path
then it can’t find the foo library (foo.dll) in your PATH or java.library.path. If it says something like:
Exception in thread "main" java.lang.UnsatisfiedLinkError: com.example.program.ClassName.foo()V
then something is wrong with the library itself in the sense that Java is not able to map a native Java function in your application to its actual native counterpart.
To start with, I would put some logging around your System.loadLibrary() call to see if that executes properly. If it throws an exception or is not in a code path that is actually executed, then you will always get the latter type of UnsatisfiedLinkError explained above.
As a sidenote, most people put their loadLibrary() calls into a static initializer block in the class with the native methods, to ensure that it is always executed exactly once:
class Foo {
static {
System.loadLibrary('foo');
}
public Foo() {
}
}