Quoted from the CREATE TABLE Syntax page:
A PRIMARY KEY can be a multiple-column
index. However, you cannot create a
multiple-column index using the
PRIMARY KEY key attribute in a column
specification. Doing so only marks
that single column as primary. You
must use a separate PRIMARY
KEY(index_col_name, …) clause.
Something like this can be used for multi-column primary keys:
CREATE TABLE
product (
category INT NOT NULL,
id INT NOT NULL,
price DECIMAL,
PRIMARY KEY(category, id)
);