ODP.NET Managed library does resolve alias, but 32-bit library does

May this workaround is suitable for you. You can query the LDAP server by your own and put the full connection string to your code.

You can resolve the connection string from LDAP with this code:

using (OracleConnection connection = new OracleConnection())
{
    connection.ConnectionString = "Data Source=" + ResolveServiceNameLdap("alias") + ";User id=user;Password=password";
    connection.Open();
}

…

  private static string ResolveServiceNameLdap(string serviceName)
  {
     string tnsAdminPath = Path.Combine(@"C:\oracle\network", "ldap.ora");
     // or something more advanced...

     // ldap.ora can contain many LDAP servers
     IEnumerable<string> directoryServers = null;

     if ( File.Exists(tnsAdminPath) ) {
        string defaultAdminContext = string.Empty;

        using ( var sr = File.OpenText(tnsAdminPath) ) {
           string line;

           while ( ( line = sr.ReadLine() ) != null ) {
              // Ignore comments or empty lines
              if ( line.StartsWith("#") || line == string.Empty )
                 continue;

              // If line starts with DEFAULT_ADMIN_CONTEXT then get its value
              if ( line.StartsWith("DEFAULT_ADMIN_CONTEXT") )
                 defaultAdminContext = line.Substring(line.IndexOf('=') + 1).Trim(new[] { '\"', ' ' });

              // If line starts with DIRECTORY_SERVERS then get its value
              if ( line.StartsWith("DIRECTORY_SERVERS") ) {
                 string[] serversPorts = line.Substring(line.IndexOf('=') + 1).Trim(new[] { '(', ')', ' ' }).Split(',');
                 directoryServers = serversPorts.SelectMany(x => {
                    // If the server includes multiple port numbers, this needs to be handled
                    string[] serverPorts = x.Split(':');
                    if ( serverPorts.Count() > 1 )
                       return serverPorts.Skip(1).Select(y => string.Format("{0}:{1}", serverPorts.First(), y));

                    return new[] { x };
                 });
              }
           }
        }

        // Iterate through each LDAP server, and try to connect
        foreach ( string directoryServer in directoryServers ) {
           // Try to connect to LDAP server with using default admin contact
           try {
              var directoryEntry = new DirectoryEntry("LDAP://" + directoryServer + "https://stackoverflow.com/" + defaultAdminContext, null, null, AuthenticationTypes.Anonymous);
              var directorySearcher = new DirectorySearcher(directoryEntry, "(&(objectclass=orclNetService)(cn=" + serviceName + "))", new[] { "orclnetdescstring" }, SearchScope.Subtree);
              SearchResult searchResult = directorySearcher.FindOne();
              var value = searchResult.Properties["orclnetdescstring"][0] as byte[];
              if ( value != null )
                 connectionString = Encoding.Default.GetString(value);

              // If the connection was successful, then not necessary to try other LDAP servers
              break;
           } catch {
              // If the connection to LDAP server not successful, try to connect to the next LDAP server
              continue;
           }
        }

        // If casting was not successful, or not found any TNS value, then result is an error 
        if ( string.IsNullOrEmpty(connectionString) ) 
           throw new Exception("TNS value not found in LDAP");

     } else {
        // If ldap.ora doesn't exist, then throw error 
        throw new FileNotFoundException("ldap.ora not found");
     }

     return connectionString;
  }