You can use any of the following:
\b #A word break and will work for both spaces and end of lines.
(^|\s) #the | means or. () is a capturing group.
/\b(stackoverflow)\b/
Also, if you don’t want to include the space in your match, you can use lookbehind/aheads.
(?<=\s|^) #to look behind the match
(stackoverflow) #the string you want. () optional
(?=\s|$) #to look ahead.