This should give you all distinct values from the table. I presume you’d want to add where clauses to select only for a particular question. However, this solution requires 5 subqueries and can be slow if your table is huge.
SELECT DISTINCT(ans) FROM (
SELECT right AS ans FROM answers
UNION
SELECT wrong1 AS ans FROM answers
UNION
SELECT wrong2 AS ans FROM answers
UNION
SELECT wrong3 AS ans FROM answers
UNION
SELECT wrong4 AS ans FROM answers
) AS Temp