I think you can find it usefull
http://docs.spring.io/spring-boot/docs/current/reference/htmlsingle/#howto-two-datasources
It shows how to define multiple datasources & assign one of them as primary.
Here is a rather full example, also contains distributes transactions – if you need it.
What you need is to create 2 configuration classes, separate the model/repository packages etc to make the config easy.
Also, in above example, it creates the data sources manually. You can avoid this using the method on spring doc, with @ConfigurationProperties annotation. Here is an example of this:
http://xantorohara.blogspot.com.tr/2013/11/spring-boot-jdbc-with-multiple.html
Hope these helps.