Newer .Net Docs now has a table to help you decide which is best to use in your situation.
From MSDN’s “New Recommendations for Using Strings in Microsoft .NET 2.0“
Summary: Code owners previously using the
InvariantCulture
for string comparison, casing, and sorting should strongly consider using a new set ofString
overloads in Microsoft .NET 2.0. Specifically, data that is designed to be culture-agnostic and linguistically irrelevant should begin specifying overloads using either theStringComparison.Ordinal
orStringComparison.OrdinalIgnoreCase
members of the newStringComparison
enumeration. These enforce a byte-by-byte comparison similar tostrcmp
that not only avoids bugs from linguistic interpretation of essentially symbolic strings, but provides better performance.