This template-argument
{.a=1, .b=2}
is not allowed according to the grammar for a template-argument which only allows the following constructs:
template-argument:
constant-expression
type-id
id-expression
A brace-init list is not any of the above constructs, it’s actually an initializer and so it cannot be used as a template-argument.
You can be explicit about the type of the object that you use as the template-argument:
Bar<Foo{.a=1, .b=2}> bar;
and this will work, since this is a constant-expression.