Gauss-Legendre Algorithm in python

  1. You forgot parentheses around 4*t:

    pi = (a+b)**2 / (4*t)
    
  2. You can use decimal to perform calculation with higher precision.

    #!/usr/bin/env python
    from __future__ import with_statement
    import decimal
    
    def pi_gauss_legendre():
        D = decimal.Decimal
        with decimal.localcontext() as ctx:
            ctx.prec += 2                
            a, b, t, p = 1, 1/D(2).sqrt(), 1/D(4), 1                
            pi = None
            while 1:
                an    = (a + b) / 2
                b     = (a * b).sqrt()
                t    -= p * (a - an) * (a - an)
                a, p  = an, 2*p
                piold = pi
                pi    = (a + b) * (a + b) / (4 * t)
                if pi == piold:  # equal within given precision
                    break
        return +pi
    
    decimal.getcontext().prec = 100
    print pi_gauss_legendre()
    

Output:

3.141592653589793238462643383279502884197169399375105820974944592307816406286208\
    998628034825342117068

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