I once wrote this function to perform that exact task:
public static string Column(int column)
{
column--;
if (column >= 0 && column < 26)
return ((char)('A' + column)).ToString();
else if (column > 25)
return Column(column / 26) + Column(column % 26 + 1);
else
throw new Exception("Invalid Column #" + (column + 1).ToString());
}