There is an option for that in Chrome’s inspector.
- Open the DevTools inspector (mac: Cmd + Shift + C , windows: Ctrl + Shift + C)
- Click on the Toggle device mode icon , located on the upper left corner of the DevTools panel. (windows: Ctrl+Shift+M, mac: Cmd+Shift+M).
- Click on the More overrides icon in the top right corner of the browser viewport to open the devtools drawer.
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Then, select Media in the emulation drawer, and check the CSS media checkbox.
This should do the trick.
Update: The menus have changed in DevTools.
It can now be found by clicking on the “three-dots” menu in the top right corner > More Tools > Rendering Settings > Emulate media > print.
Source: Google DevTools page*