Following worked for me:
ln -s /Applications/Xcode.app/Contents/Developer/Platforms/MacOSX.platform/Developer/SDKs/MacOSX10.9.sdk/System/Library/Frameworks/Tk.framework/Versions/8.5/Headers/X11 /usr/local/include/X11
sudo pip install pil
UPDATE:
But there is more correct solution below, provided by Will.
open your terminal and execute:
xcode-select --install