Flattening of a 1 row table into a key-value pair table

A version where there is no dynamic involved. If you have column names that is invalid to use as element names in XML this will fail.

select T2.N.value('local-name(.)', 'nvarchar(128)') as [Key],
       T2.N.value('text()[1]', 'nvarchar(max)') as Value
from (select *
      from TableA
      for xml path(''), type) as T1(X)
  cross apply T1.X.nodes('/*') as T2(N)

A working sample:

declare @T table
(
  Column1 varchar(10), 
  Column2 varchar(10), 
  Column3 varchar(10)
)

insert into @T values('V1','V2','V3')

select T2.N.value('local-name(.)', 'nvarchar(128)') as [Key],
       T2.N.value('text()[1]', 'nvarchar(max)') as Value
from (select *
      from @T
      for xml path(''), type) as T1(X)
  cross apply T1.X.nodes('/*') as T2(N)

Result:

Key                  Value
-------------------- -----
Column1              V1
Column2              V2
Column3              V3

Update

For a query with more than one table you could use for xml auto to get the table names in the XML. Note, if you use alias for table names in the query you will get the alias instead.

select X2.N.value('local-name(..)', 'nvarchar(128)') as TableName,
       X2.N.value('local-name(.)', 'nvarchar(128)') as [Key],
       X2.N.value('text()[1]', 'nvarchar(max)') as Value
from (
     -- Your query starts here
     select T1.T1ID,
            T1.T1Col,
            T2.T2ID,
            T2.T2Col
     from T1
       inner join T2
         on T1.T1ID = T2.T1ID
     -- Your query ends here
     for xml auto, elements, type     
     ) as X1(X)
  cross apply X1.X.nodes('//*[text()]') as X2(N)

SQL Fiddle