If you have updated to Chrome Version 36.0.x and Selenium 2.42, Martins solution no longer works.
It seems to have been updated. You now can use the following code
ChromeOptions options = new ChromeOptions();
options.AddUserProfilePreference(string preferenceName, object preferenceValue);
I currently use it to change my Printer settings to “Save as PDF” instead of the default using this code as an example
ChromeOptions options = new ChromeOptions();
options.AddUserProfilePreference("printing.print_preview_sticky_settings.appState", "{\"version\":2,\"isGcpPromoDismissed\":false,\"selectedDestinationId\":\"Save as PDF\");
I thought Martin’s solution was very good and accurate, but it suddenly stopped working for me, so naturally I had to see if I could find a solution.