You have a string representing a JSON serialized JavaScript object. You need to deserialize it back to a JavaScript object before being able to loop through its properties. Otherwise you will be looping through each individual character of this string.
var resultJSON = '{"FirstName":"John","LastName":"Doe","Email":"[email protected]","Phone":"123 dead drive"}';
var result = $.parseJSON(resultJSON);
$.each(result, function(k, v) {
//display the key and value pair
alert(k + ' is ' + v);
});