As you correctly note, there is no way to mix bitness in the same process. You need a separate process for your 32-bit part.
I think hosting a WCF Service is the right way to go. Your link only talks about wcfsvchost. I am pretty sure you can create your own Windows Service, and host the WCF service in that on 32 bit.
See this link: How to host a WCF service in a managed application. You can host your service in any managed application, including a Windows Service, and run it under the bitness you like.
This is the amount of code required to self-host a WCF service in your application, assuming you have just created a new service called MyService, and the appropiate configuration has been added to app.config:
class Program
{
static void Main(string[] args)
{
using(ServiceHost host = new ServiceHost(typeof(MyService), new Uri[0]))
{
host.Open();
Console.ReadKey();
}
}
}
The above program will run just as well, also if you compile it explicitly as 32 or 64 bit.